Tannin-modified soybean protein concentrate for wood adhesive

Leandro Esposito

https://orcid.org/0000-0003-0852-6392

Argentina

Instituto de Investigaciones en Ciencia y Tecnología de Materiales. (INTEMA); Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET); Universidad Nacional de Mar del Plata (UNMdP)

Emiliano Manuel Ciannamea

https://orcid.org/0000-0001-6982-1550

Argentina

Instituto de Investigaciones en Ciencia y Tecnología de Materiales. (INTEMA); Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET); Universidad Nacional de Mar del Plata (UNMdP)

Ignacio Solaberrieta

https://orcid.org/0000-0002-9587-6325

Argentina

Instituto de Investigaciones en Ciencia y Tecnología de Materiales. (INTEMA); Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET); Universidad Nacional de Mar del Plata (UNMdP)

Juan Carlos Piter

https://orcid.org/0000-0001-7473-7994

Argentina

Grupo de Estudio de Maderas (GEMA); Universidad Tecnológica Nacional

Departamento de Ingeniería Civil, Facultad Regional Concepción del Uruguay

Roxana Alejandra Ruseckaite

https://orcid.org/0000-0002-7409-5546

Argentina

Instituto de Investigaciones en Ciencia y Tecnología de Materiales. (INTEMA); Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET); Universidad Nacional de Mar del Plata (UNMdP)

Pablo Marcelo Stefani

https://orcid.org/0000-0002-8140-4415

Argentina

Instituto de Investigaciones en Ciencia y Tecnología de Materiales. (INTEMA); Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET); Universidad Nacional de Mar del Plata (UNMdP)

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Accepted: 2021-11-22

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Published: 2022-01-31

DOI: https://doi.org/10.4995/jarte.2022.15962
Funding Data

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Keywords:

soybean protein concentrate, mimosa tannin, rheology properties, wettability, shear strength

Supporting agencies:

Agencia Nacional de promoción Científica y Tecnológica (ANPCyT) under Grant PICT 2016 0445

Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET)

Universidad Nacional de Mar del Plata (UNMdP)

Abstract:

Soybean protein concentrate (SPC) modified with condensed mimosa tannin (CT) were employed as eco-friendly and formaldehyde-free adhesives for glued-wood joints. Eucalyptus grandis wood boards free of knots and cracks were used as substrate. Thermogravimetric analysis (TGA) showed that tannin provided higher thermal stability to the adhesive, which allowed expanding the temperature range for hot pressing. Apparent viscosity and dynamic angle contact were measured to evaluate the influence of tannin content on rheological behaviour and the wettability process. A classic shear-thinning behaviour was observed for all adhesives. Apparent viscosity and equilibrium contact angle reached a maximum value for low CT content. This effect was attributed to the existence of associative interactions between CT and SPC. Bonding quality parameters (wood failure percentage and shear strength) of the glued-wood joints were measured according to EN 302-1:2004 standard. 1 % CT w/w on SPC adhesive showed the best performance for dry conditions. These adhesives were suitable for glued-wood joints for indoor environments.

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